Welcome to the forums
It's normal/common for there to be one or two cores lower than the rest and not an awful lot you can do about it.
I would recommend the Thermalright Ultra Extreme if your budget allows it, and a good quality fan.
The best way to get into watercooling is to read up. Decide what you want from the cooling and then buy accordingly. There's no point in buying super high end stuff unless you are going for large overclocks. On the other hand, you might want total silence, and end up with a passive unit.
You can buy pre built external units, or you could buy a small case and put all the watercooling gear in that.
